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Nitrogen · Hero product · VAN exclusive

Vital Urea

Sulfur Coated Urea — N 32% min · S 13% min

Nitrogen that feeds the crop, not the air. In Pakistan’s alkaline, hot soils a large share of plain urea’s nitrogen is lost before the plant can use it. Vital Urea’s sulfur coating releases N in step with crop demand — and the sulfur itself conditions the root zone, temporarily acidifying it to unlock fixed phosphorus and zinc.

Broadcast Sowing / basal + top-dress VAN exclusive Patent No. 144684 · PS 217-2023
Vital Urea 25 kg bag
32% N · 13% Sguaranteed analysis — at least 8.0 kg of nitrogen and 3.25 kg of sulfur in every 25 kg bag
7–18 daysrelease profile, depending on climate and application method
No. 144684Pakistan Patent on the sulfur-coating technology — Government of Pakistan Patent Office
PS 217-2023PSQCA standard · licence CM/L-4126/2025 · released through VAN’s PNAC-accredited laboratory, LAB 336
The problem

Only about a quarter of applied nitrogen ends up in Pakistan’s crops.

Nitrogen loss in Pakistani soil is chemistry, not carelessness. Volatilisation, nitrification and leaching all act on nitrogen that is dissolved in the soil solution — and a granule of plain urea dissolves all at once, on ground that is hot and alkaline. Everything that follows on this page is one idea: nitrogen still inside a granule is not in the soil solution, and what has not been released yet cannot be lost yet.

The full case for moving off plain urea — with its sources — is on the national picture page. This page is about the coating: what it does, what it cannot do, and why it is made of sulfur.

Roughly a quarter reaches the crop here — against about 72% in the United States

Share of applied nitrogen taken up by the crop, national cropland estimate

Pakistan
~25%
United States
~72%

Source: Lassaletta et al. (2014), Environmental Research Letters 9:105011. Vital Urea exists because of the first number.

What a bag buys

One 25 kg bag stood against a 50 kg bag of plain urea — and the growth was comparable.

Khaliqabad field programme with Rafhan Maize Products, 2023 — five grower sites picked by their agronomy team, application in August through harvest in October, assessments at 12 and 24 days. The comparison was deliberately uneven.

Two bags, drawn to one scale of nitrogen — what the label says, and when it arrives

Kilograms of N are registered label contents. Release behaviour is the mechanism each product is built on.

Plain urea50 kg — the default the market buys

on the label

23 kg N

how it arrives

all at once, the day it dissolves

from that moment, volatilisation, nitrification and leaching act on all of it

Vital Urea25 kg — openly a smaller bag

on the label

8 kg N

+ at least 3.25 kg of sulfur in the same granules

how it arrives

metered over 7–18 days

released while there is a root ready to take it — what is still inside the granule cannot be lost yet

What the five sites recorded: comparable crop growth — shoot length, colour, leaf number, vigour — from the 25 kg bag on roughly a third of the applied nitrogen, with better uniformity of plant height, grain formation and milk-line development also observed. Cob size and length showed no difference. And what this was not: an observational field programme, not a replicated randomised trial — no independent yield measurement was recorded, and VAN reports it as exactly that. If you need replicated trial data for a purchasing decision, ask — where it exists, you will get it.

The coating

A barrier with a deliberate failure rate.

The sulfur shell is not a wrapper. Water finds its way in through pores and micro-cracks, dissolves the urea inside, and the solution diffuses back out through the same paths. Nothing releases until water gets in — that is what produces the 7–18 day profile.

Three things move it inside that range: soil temperature, because diffusion and the microbes both run faster when it is hot; moisture, because a dry seedbed releases nothing; and handling, because a granule crushed at spreading has no barrier left and behaves like plain urea from the moment it hits the ground.

What it does not do. A coating does not stop volatilisation — it reduces how much nitrogen is exposed to it at any one moment. Nitrogen released into hot alkaline soil behaves like any other nitrogen released into hot alkaline soil. Placement and irrigation timing still matter, and no coating substitutes for either.

The same nitrogen, arriving while there is a root ready to take it

Schematic, not a measurement — the demand curve is drawn for shape, and no axis carries a figure VAN has not published

Plain urea NH₃ ↑  ammonia, straight to the air NO₃⁻ ↓  nitrate, past the root zone N₂O / N₂ ↑  denitrified in wet ground Vital Urea metered out across 7–18 days what the crop is asking for 036912151821 days after application nitrogen in the soil solution

Both curves carry the same nitrogen — the only difference is when it arrives.

Why sulfur

Three ways to slow urea down. Only one of them is also plant food.

Polymer coating

accurate, inert

Controls release accurately and delivers nothing else. Adds no nutrient, and the polymer stays in the soil after the nitrogen has gone.

Chemical inhibitors

slow the reactions, not the release

Imported, dose-sensitive, temperature-sensitive — and they add no nutrient of their own.

Sulfur coating

the one VAN chose

Controls release and is the only one of the three that is itself a nutrient and itself chemically active in the soil. The next section is what that buys.

A sixth of the bag is coating, and the numbers are kept honest: 3.25 kg is the registered sulfur nutrient — 13% of 25 kg under PS 217-2023. The sulfur VAN charges to the coater is 80% pure, so delivering it means about 4.06 kg of sulfur material in the bag — arithmetic, not a batch assay. What a certificate carries is the measured elemental sulfur, most recently 13.27% on batch VU25186.

The chemistry

Why the result is not “nitrogen plus sulfur.”

Two pictures. The shell geometry is what makes the sulfur work, and the sulfur is what lets the nitrogen finish as yield.

Sulfur only becomes plant food at its surface — and a micronised shell is nearly all surface

The same mass of elemental sulfur in three geometries; oxidation to sulfate happens where soil touches sulfur

one lump almost no surface fine, dispersed all surface, goes everywhere fine, on the granule all surface, stays with the N 90% S pastille 0.0006 / day fine S in soil 0.02 / day — about 33× faster measured oxidation rate of elemental sulfur, per day (Degryse et al., 2016)

Rapid oxidation calls for particles finer than about 20 µm, well dispersed (Bremer, 2022) — which is what a shell micronised onto a granule is. The reaction is biological and roughly triples to quadruples for every 10 °C of soil warming (Janzen & Bettany, 1987): the heat that destroys surface urea is the heat that runs this. 2 S⁰ + 3 O₂ + 2 H₂O → 2 SO₄²⁻ + 4 H⁺ — four protons per two atoms of sulfur.

Nitrogen that arrives without sulfur does not become yield

Both elements are built into protein together; where sulfur is short, absorbed nitrogen accumulates unfinished

N no sulfur — gate shut nitrogen the plant already absorbed parks as nitrate and soluble amines N S sulfur present — gate open amino acids → protein → grain the nitrogen becomes yield

Wheat builds protein at about fifteen parts nitrogen to one part sulfur, and above seventeen-to-one yield falls away — so each kilogram of sulfur the crop is short of is roughly 10–15 kg of nitrogen that cannot be finished into protein (Grzebisz et al., 2022; Zapałowska et al., 2026; Wan et al., 2012 — a cereal ratio; brassicas run lower). The protons from the oxidation land exactly where the nitrogen is — dissolving calcium-held phosphorus and freeing zinc, iron and manganese (Khoshru et al., 2023).

Where this stops being certain. Alkaline soil is a harder place to oxidise sulfur, not an easier one: in a controlled comparison, elemental sulfur lowered the pH of an alkaline soil only where a sulfur-oxidising inoculant was added with it (Mattiello et al., 2017). Either way it is a microsite effect — a zone around each granule, for the weeks it is releasing. It will not move a soil test, and VAN does not claim it does. Raising that oxidation rate deliberately is a live VAN research track, not a product claim.

One granule, not a blend

Coated on every granule — the argument that decides the other three.

Everything above needs the nitrogen and the sulfur in the same place at the same moment. A mixture cannot promise that.

Two materials in one bag separate; a coated granule cannot separate from itself

Blends segregate by size and density, and the wider the size spread, the more severe it gets (Antille et al., 2013)

blended in the bag coated on the granule handling · hopper · spreader disc the same journey one end of the field gets the nitrogen, the other gets the sulfur every granule carries both, to the same spot

The shell is also what creates the surface in the first figure — the same sulfur as a lump would still be sitting there next season.

What is claimed here and what is not. Uniformity is a batch record, not a slogan. What VAN publishes is the declared analysis — 32% N and 13% S, registered against PS 217-2023 and released through VAN’s PNAC-accredited laboratory. Coating weight is measured per batch; VAN does not publish the figure, and will provide it against a batch number on the same terms as the certificate. No granule-to-granule figure is claimed on this page because none is published — not because none is measured.

The evidence

What has been tested, and how it was tested.

The field programme above is one of two proofs. The second is a published, replicated trial. Nothing below is an estimate.

Published trial — maize, VAN’s trial station, 2024

A randomised complete block design with three replications on DK-6321 maize compared nitrogen strategies. Two stage-timed applications of sulfur-coated urea — at the 4–6 leaf stage and again twenty days later at the 8–12 leaf stage — outperformed a five-application programme of conventional urea followed by calcium ammonium nitrate across the growth and yield parameters measured.

Why we cite it for the finding and not a headline number: the paper reports its own yield inconsistently between its results table and its discussion. We would rather tell you that here than have you find it.

Umair, A., Manzoor, M., Saleem, M. S., et al. (2025). Planta Animalia 4(3), 129–135. DOI 10.71454/PA.004.03.0126.

What the published research establishes about coated urea — not measurements of Vital Urea

Coated urea raises nitrogen recovery against uncoated urea. Zhao, Gao & Gao (2025), Agriculture 15(14):1554 — a two-year field study reporting higher nitrogen recovery efficiency, agronomic efficiency and grain yield for sulfur-coated urea than for conventional urea in rice.

The effect holds in Pakistani conditions. Ghafoor, Rahman & Ali et al. (2021), Environmental Science and Pollution Research — coated urea sources improved growth, yield and nitrogen use efficiency and reduced nitrogen losses in wheat under an arid Pakistani environment.

Elemental sulfur releases phosphorus that alkaline soil has locked away. Nadeem, Hanif & Khan (2022), Archives of Agronomy and Soil Science 69(9):1494–1502 — elemental sulfur with a sulfur-oxidising inoculant raised phosphorus availability and improved wheat growth and yield in calcareous soil.

Sources for the chemistry sections

Degryse, F., et al. (2016). Soil Science Society of America Journal 80(2), 294–305. doi:10.2136/sssaj2015.06.0237.

Bremer, E. (2022). Crops & Soils 56(1), 34–37. doi:10.1002/crso.20241.

Janzen, H. H., & Bettany, J. R. (1987). Canadian Journal of Soil Science 67(3), 609–618. doi:10.4141/cjss87-057 — temperature response as summarised by Degryse et al. (2016).

Grzebisz, W., Zielewicz, W., & Przygocka-Cyna, K. (2022). Agronomy 13(1), 66. doi:10.3390/agronomy13010066.

Elbasyoni, I. S., et al. (2026). Life 16(5), 795. doi:10.3390/life16050795.

Khoshru, B., et al. (2023). Bacteria 2(2), 98–115. doi:10.3390/bacteria2020008.

Mattiello, E. M., et al. (2017). Journal of Agricultural and Food Chemistry 65(6), 1108–1115. doi:10.1021/acs.jafc.6b04586.

Zapałowska, A., et al. (2026). Molecules 31(1), 160. doi:10.3390/molecules31010160 — the N:S optima, summarising Sedlár et al.

Wan, Y., Shewry, P. R., & Hawkesford, M. J. (2012). Journal of Cereal Science 56(1), 72–80. doi:10.1016/j.jcs.2011.10.014 — critical grain S 1.2 mg/g and N:S 17:1.

Antille, D. L., Sakrabani, R., & Tyrrel, S. (2013). Applied and Environmental Soil Science 2013, 694597. doi:10.1155/2013/694597 — reporting the segregation thresholds of Miserque and Pirard.

Lassaletta, L., et al. (2014). Environmental Research Letters 9:105011 — the national nitrogen uptake shares.

In the field

Where it goes, and how much.

From the locked VAN crop nutrition plans, 2025 set. This table is a sample — Vital Urea appears in 27 of the 28 published programmes.

CropStageDose per acreMethod
GarlicLand preparation1 bag (25 kg)Broadcasting
GarlicGermination1 bag (25 kg)Broadcast
SesameGermination1 bag (25 kg)Side dressing / broadcasting
SesameEarly growth½ bag (12.5 kg)Side dressing / broadcasting
SoybeanLand preparation½ bag (12.5 kg)Broadcasting
LentilLand preparation½ bag (12.5 kg)Broadcasting
Mungbean & mashLand preparation½ bag (12.5 kg)Broadcasting
CanolaLand preparation1 bag (25 kg)Side dressing / broadcasting

Growing a different crop? The full stage-by-stage programme for 28 crops is in the crop nutrition plans — and how the bag is applied changes the answer, so the application guidance sits beside them.

Behind the bag

What is behind the bag.

Registration & standardPSQCA PS 217-2023 · Licence CM/L-4126/2025 · Pakistan Patent No. 144684
Pack size25 kg bag
QualityEvery batch released through VAN’s own PNAC-accredited laboratory — ISO/IEC 17025:2017, LAB 336
Certificate on requestSend the batch number off the bag and VAN sends the certificate of analysis for that batch — the elemental-sulfur figure on it is measured, most recently 13.27% on batch VU25186.

A VAN flagship — exclusively ours

Vital Urea stays a VAN brand: the sulfur-coating technology is protected by Pakistan Patent No. 144684. Carry it through the distribution network — territory and volume terms available.

Sources for this page. Analysis, standard, licence and patent — the registered TDS and van.com.pk. Release mechanism and coating chemistry — the peer-reviewed sources listed in the evidence section, cited for the technologies they studied, under the conditions each study describes; none is a measurement of Vital Urea. Field programme — Khaliqabad 2023, with Rafhan Maize Products. Replicated trial — Umair et al. (2025), Planta Animalia 4(3). National nitrogen uptake — Lassaletta et al. (2014). Doses — the locked VAN crop nutrition plans, 2025 set. No performance percentage is claimed for Vital Urea anywhere on this page; the two proofs are reported with their limits stated.
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