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Phosphorus · Hero product

Green Phosphate

6-32-0 · humic-coated acidic phosphate

Granular phosphorus engineered for calcareous soils. The humic coating and the granule’s own free-acid chemistry keep P available in the root zone instead of locking up as calcium phosphate — VAN’s core answer to Pakistan’s phosphorus-use-efficiency problem.

BroadcastSowing / basal Own-brand available PS 933-2026 · CM/L-2719/2023
Green Phosphate 35 kg bag
6-32-0N 6% · P₂O₅ 32% — the registered grade
250 g/Lmoderately soluble — band placement or broadcasting
26 of 28published crop programmes carry it, each with a dose and a stage
50 · 35 kgtwo pack sizes, one analysis, released through LAB 336
The problem

Pakistan imports phosphate. Then the soil takes most of it back.

80–95% of Pakistani soils are phosphorus-deficient, and soil pH sits far above the 6.0–7.0 window where phosphorus stays available. On calcareous ground, free calcium captures most of what a farmer spreads before a root ever reaches it.

Phosphorus is not lost to the air like nitrogen, or leached like potassium. It is still there — but in the season the farmer paid for it, the crop recovers only about a fifth. It is the largest single line in Pakistan’s fertilizer import bill, bought in dollars and locked up in the first season.

Figures as cited in VAN’s 2026 product literature — Ahmad, M. et al. (2022), Sustainability 14(13), 7669.

Phosphorus-use efficiency

The label counts kilograms in the bag. The crop counts kilograms it can take.

DAP’s label says 46. Green Phosphate’s says 32. The label number is about the bag — the number that pays the farmer is about the root. Phosphorus-use efficiency is that second number: of the kilograms you paid for, how many the crop can actually take.

A 50 kg bag, on calcareous ground — what the label says, and what gets through

Kilograms of P₂O₅, drawn to one scale. Label contents are registered analysis; the DAP availability figure is derived from the cited ~20% first-season recovery of conventional phosphate on this ground.

DAPthe default the market buys

on the label

23 kg P₂O₅

reaches the crop

~4.6 kg this season — the other ~18 kg, the soil holds

Green Phosphate6-32-0 · engineered against fixation

on the label — openly fewer

16 kg P₂O₅

reaches the crop

protected three ways

surface acid · humic chelation · phosphatase sugars — VAN prints the figure when its own replicated trial signs off

How to read this honestly: the DAP arithmetic uses only published figures — 46% × 50 kg = 23 kg, and the cited ~20% availability of conventional phosphate on calcareous ground. For Green Phosphate, VAN prints the reaches-the-crop number when its own replicated trial signs off, not before. What is already measurable is the chemistry that removes the conditions fixation needs — and the certificate of analysis for every batch, on request against the batch number.

The chemistry

Availability has a narrow pH window. Pakistan sits outside it.

How much applied phosphorus stays plant-available, by soil pH — fixed by iron and aluminium below pH 6, by calcium above pH 7.

The shape of this relationship is standard soil chemistry. The bars are illustrative — not a measurement of any particular field. Green Phosphate carries its own free phosphoric acid at the granule surface while its bulk reaction stays near neutral — measured at pH (1%) 6.5–7.5 — so the chemistry in the few centimetres that matter is not the alkaline zone that fixes phosphate.

The technology

Three things happen around this granule that do not happen around DAP.

What is engineered in, beyond the two declared nutrients.

1 · ACID

Acid at the granule surface

The granule carries 3% free phosphoric acid — a measured COA figure — while its bulk reaction stays near neutral at pH (1%) 6.5–7.5. The phosphate dissolves into a micro-environment that is not the alkaline reaction zone DAP creates, so it stays in solution long enough for a root to find it.

2 · HUMIC

A humic coating

Humic substances are coated onto the granule. They chelate the calcium, iron and aluminium that would otherwise capture the phosphate, and they improve soil structure and biology where they land.

3 · SUGARS

Fermentable sugars

Bio-available fermentable sugars feed the soil microbial population, raising phosphatase activity — the enzyme route by which stable organic phosphorus is mineralised back into an available form.

4 · RESTRAINT

Restrained nitrogen

Nitrogen is held at a basal 6% rather than loaded in. High ammoniacal nitrogen at sowing risks ammonia injury to a germinating seedling; this grade is built to sit safely beside seed.

Magnesium and a biostimulant fraction are also part of the formulation. They are named without figures because they are not label-declared.

Against the default

Green Phosphate and DAP are not the same trade.

DAP is the phosphate most Pakistani growers buy. This is what differs.

Di-ammonium phosphate

A true salt, high in ammoniacal nitrogen, alkaline in its immediate reaction zone.
  • Excess ammoniacal nitrogen at the basal stage — risk of seedling ammonia injury
  • Creates an alkaline micro-zone — the condition that fixes phosphate
  • No humic acid, no biostimulant, no organic-matter contribution
  • Phosphorus efficiency low on calcareous ground

Green Phosphate

An acidic, humic-coated granule carrying only as much nitrogen as a basal dose needs.
  • Controlled nitrogen at 6% — safe next to germinating seed
  • No alkaline reaction zone — phosphate stays available where the root is
  • Humic acid and fermentable sugars raise soil biology and phosphatase activity
  • Phosphorus protected from fixation for longer

VAN publishes no head-to-head efficiency percentage between the two. The chemistry is the argument.

Guaranteed analysis

What the label declares, and what the lab measured.

A green ✓ COA means VAN’s PNAC-accredited laboratory measured it. From the registered Technical Data Sheet.

ParameterSpecificationStatusPhysical propertyValueStatus
Nitrogen (N)6%✓ COAPhysical statusGranular✓ COA
Phosphorus (P₂O₅)32%✓ COAColourBrown✓ COA
Free ammonia<250 ppm✓ COAParticle size1–3 mm✓ COA
Biuret1.5%✓ COAMoisture<1%✓ COA
Free H₃PO₄3%✓ COApH (1%)6.5–7.5✓ COA
Other ingredientsto 100%Solubility250 g/L
Right place

Phosphorus does not travel. Placement is most of the agronomy.

Three ways in, in order of preference — the root has to reach the granule, because the granule will not reach the root.

1 · BEST

With the seed drill

Places the granule in the seed row at sowing, exactly where the first roots will emerge, in one pass.

2

Band placement

A concentrated band beside or below the row — saturates the fixing capacity of a small soil volume rather than feeding all of it.

3 · FALLBACK

Broadcasting

Even spread at land preparation, worked in. Simplest and most common — and the one that exposes the most granule surface to the most soil.

Application & dosage

From the locked VAN crop nutrition plans.

This table is a sample — Green Phosphate appears in 26 of the 28 published programmes. Rates are per acre; a soil test is the rate to finish with.

CropStageDose per acreMethod
GarlicLand preparation2 bags (100 kg)Broadcasting
SesameLand preparation1 bag (50 kg)Broadcasting
SoybeanLand preparation½ bag (25 kg)Broadcasting
LentilLand preparation½ bag (25 kg)Broadcasting
Mungbean & MashLand preparation½ bag (25 kg)Broadcasting
CanolaLand preparation1 bag (50 kg)Side dressing / broadcasting
ChickpeaLand preparation½ bag (25 kg)Broadcasting
WatermelonLand preparation1.5 bags (75 kg)Broadcasting

Growing a different crop? The full stage-by-stage programme for 28 crops is in the crop nutrition plans on van.com.pk/crops. For the mid-season rise in phosphorus demand, VAN’s answer is a soluble fertigation phosphate — V-Phosphate — applied at the stage the second peak occurs.

Standards, packs & documents

What is behind the bag.

Registration & standardPS 933-2026 · Licence CM/L-2719/2023, printed on the pack
Pack sizes50 kg bag · 35 kg bag — granular; a powder grade is also produced
QualityEvery batch tested before it ships in VAN’s PNAC-accredited laboratory — ISO/IEC 17025:2017, LAB 336
Certificate on requestSend the batch number off the bag and VAN sends the certificate of analysis for that batch. No charge, no sample, no form.

Available for own-brand manufacturing

Green Phosphate’s specification can be produced under your brand — same line, same QC, your name on the pack. Or carry it as a VAN brand through the distributor programme. Two further grades extend it — NP 5-40 and NP 8-38 + sulfur — held unbranded in VAN’s formulation library for a partner to take.

Sources for this page. Analysis, standard and licence — the registered TDS and van.com.pk. Phosphorus deficiency and fixation — Ahmad, M. et al. (2022), Managing phosphorus availability from organic and inorganic sources for optimum wheat production in calcareous soils, Sustainability 14(13), 7669. Phosphatase and molasses — Wu, Q. et al. (2023), Sugar Tech 25(3), 552–561. pH–fixation relationship — standard soil chemistry: Fe/Al below pH 6, Ca above pH 7. Nutrient interactions — after Mulder. Crop programmes — van.com.pk/crops, 26 published programmes name Green Phosphate. No yield figure appears on this page; VAN publishes performance figures only where a verified trial number exists.
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